Flexible foam raw materials are the liquid chemicals that form flexible polyurethane foam: a polyol, an isocyanate (mostly TDI) and water, plus catalysts, a surfactant and other additives when needed. The mix is foamed as a large block (slabstock) or inside a mould. The right system depends on the product you make, the target density and hardness, the foam type (conventional, HR, memory) and your production method.

1. What are flexible foam raw materials?

Flexible polyurethane foam (PU foam) is the soft material inside sofa cushions, mattresses and car seats. The foam is generally open-cell, so air can flow through it, and it springs back when a load is removed. The liquid chemicals it is made from are its raw materials. The wider picture is in our guides "What Is Polyurethane?" and "What Is Polyurethane Foam?".

This guide is about those liquid chemicals. The finished foam block that is cut and upholstered is the product made from them; Section 4 explains how that block is made. Cleaning sponges are outside the scope of this guide.

2. What is flexible polyurethane foam made of?

According to the material information sheet of EUROPUR, the European association of flexible polyurethane foam block manufacturers, flexible foam forms from diisocyanates, polyols (a large share) and water (a small share), and additives are used in small concentrations. The table gives a general overview of each raw material and its role in the mix.

Raw materialWhat it doesRole in the mix
Polyol (mostly polyether)Forms the flexible polymer chainsMain component
Isocyanate (mostly TDI, sometimes MDI)Reacts with the polyol and with water and builds the polymer networkMain component
WaterReacts with the isocyanate and releases carbon dioxide, the gas that blows the foamMinor component, small share
CatalystsSpeed up and balance the reactionsSmall additive
SurfactantHelps the foam form an even, stable cell structureSmall additive
Other additives (for example flame retardants, pigments)Influence specific properties, for example flame resistance, or add colourSmall additive, only when needed

Which additives are used, and how much of each, depends on the specification of the foam to be produced (EUROPUR).

Polyol: polyether and polyester

Polyether polyols are the more widely used type for flexible foam, and polyester polyols are less common in soft foams; EUROPUR lists both foam types. The polyol type is one of the factors that shape the properties of the finished foam.

Isocyanate: TDI and MDI

EUROPUR names TDI (toluene diisocyanate) as the main diisocyanate for flexible foam. Moulded foams are more often made with MDI (methylene diphenyl diisocyanate), and memory foam can also be made with MDI. For more detail, see our guide "Polyol and Isocyanate".

3. How is flexible foam made?

In flexible foam production, the liquid components are metered and mixed, and the mix then foams, rises and solidifies. The foaming comes from carbon dioxide, which is released when the isocyanate reacts with water, while the reaction of the polyol with the isocyanate builds the polymer that gives the foam its structure. The details depend on the system and on the production line.

Safety when handling the raw materials

Isocyanates can cause allergic sensitisation of the skin and airways, so they should be used by trained people with suitable protective equipment. In the EU, Regulation 2020/1149 requires industrial and professional users of products with 0.1 percent by weight or more of diisocyanates to be trained before use; this has applied since 24 August 2023 and the training must be renewed at least every five years. According to EUROPUR, the diisocyanates are consumed in the reaction, and cured flexible polyurethane foam is an article under REACH, not a hazardous product. That statement covers cured flexible foam only.

4. What is slabstock? Slabstock and moulded foam

Slabstock, or flexible slabstock foam, is flexible polyurethane foam made as a large, continuous block that is cut into shape afterwards. The mix is laid onto a moving conveyor, rises freely and solidifies, and the block is later cut into sheets, rolls or shaped parts. According to EUROPUR, most of the slabstock foam made in Europe goes into mattresses and furniture, and a smaller part into transportation.

Moulded (molded) flexible polyurethane foam is poured or injected into a closed mould, so the part comes out close to its final shape. This route can make shapes that are hard to cut from a block and can combine foam with parts such as a metal frame. Mould costs are high, so the US Polyurethane Foam Association (PFA) notes that moulding is typically reserved for high production runs. Almost all car seats in Europe are made of flexible moulded foam (EUROPUR). A mould release agent helps the part leave the mould cleanly. Moulded foam is made by hot cure or cold cure processes; today the dominant one worldwide is cold cure foam, also known as high resilience (HR) foam (Euromoulders).

FeatureSlabstock (block) foamMoulded foam
How it is madeContinuous line: the mix rises freely on a conveyor and the block is cut afterwardsThe mix goes into a closed mould, one part at a time
Typical useMattresses, furniture cushions, packagingCar seats, headrests, office furniture parts

5. Types of flexible foam: conventional, HR, memory, rebonded

EUROPUR names three common families of flexible foam: standard ether, high resilience (HR) and visco-elastic. They differ in density, hardness, tensile strength and viscosity, among other properties. Rebonded foam, made from shredded foam scrap, is a separate product.

TypeWhat it isTypical use
Conventional (standard ether)Basic cushioning foam; may lack long-term durability and resilienceBudget mattresses, base layers
HR (high resilience)Higher resilience than conventional foam and generally better support and durability; made as slabstock and as moulded foamPremium mattresses, seating, car seats
Memory (viscoelastic)Recovers slowly, very low resilience, follows the body shape (see section 6)Mattress and pillow layers, medical cushions
RebondedShredded foam pieces pressed together with a binder (ISOPA)Carpet underlay, sports mats, flooring, packaging

For the difference between flexible and rigid foam, see "Rigid vs Flexible Polyurethane Systems"; for rebonded foam and recycling, see "Polyurethane Recycling Methods".

6. What is memory foam? (viscoelastic foam)

Memory foam (viscoelastic or "visco" foam) is a polyurethane foam that recovers slowly after it is pressed. It consists mainly of polyurethane with additional chemicals that increase its viscosity and density. Its cells are open and its resilience is very low. Its behaviour depends on temperature, and it typically softens with body heat. It was developed in 1966 under a NASA contract to improve the protection and comfort of airplane seats.

Memory foam is used in mattresses, pillows and medical cushions. A mattress often combines several types of foam in layers (EUROPUR). A memory foam mattress is usually denser, and therefore heavier, than other foam mattresses. For our systems, see "Viscoelastic Polyurethane: Memory Foam Systems" and "Memory Foam Systems for Mattresses & Pillows".

7. What does density mean? How it differs from hardness

Density is the mass of foam per cubic metre, in kg/m³. According to PFA it indicates comfort, support, durability and cost: higher density foam generally keeps its properties longer but uses more material and costs more. Flexible foam is made over a very wide range of densities, depending on the type and the application.

Hardness is a separate property: it is measured by the force needed to press the foam by a given amount. Standardised test methods such as ISO 2439 or ASTM D3574 are used.

What sets the hardness at a given density?

Density and hardness are set independently: PFA states that a high density foam can be soft and a low density foam can be firm. Hardness is shaped by the formulation, the foam type and other factors, and a hardness value means little without the test method it was measured with.

PropertyWhat it isWhy it matters
Density (kg/m³)Mass of foam per cubic metreIndicates durability, support and cost
HardnessForce needed to press the foam by a given amountHow the foam feels when you sit or lie on it
ResilienceHow much the foam springs backLinked to comfort; very low in memory foam
Compression setPermanent loss of height after the foam has been compressedDurability in use, for example body impressions on a mattress

8. How to choose flexible foam raw materials by application

Start with the product. Most of the flexible foam made in Europe goes into bedding and upholstery (EUROPUR), but each application asks for something different.

ApplicationWhat matters mostUsual foam type and method
Furniture cushionsSupport, comfort, durability, fire safety requirementsConventional or HR; slabstock cut to shape, or moulded
MattressesSupport, comfort, durability, emission and fire safety requirementsConventional, HR and memory foam, often in layers; slabstock
Car seatsComfort, durability under repeated loading, fire and emission requirements for vehicle interiorsHR (cold cure), moulded
PackagingShock absorption, a shape that fits the packed itemSlabstock cut to shape

The right density and hardness depend on the product, the load it carries and the foam type. They are best set together with the foam supplier, who needs to know the use and the production method (see section 9).

Choosing by production method

A continuous slabstock line and a moulding line use different systems, so the production method is part of the choice. A system house formulates the blend to suit your process and production line, and our technical team supports you with this. For seating, see Cold-Cure & Slabstock Foam Systems for Seating; for all flexible systems, see Flexible Polyurethane Foam Systems.

9. What to tell the supplier when you specify flexible foam raw materials

Foam makers buy raw materials in two ways: separately (polyol, isocyanate and additives) to build their own recipe, or as a matched ready system from a system house. A ready system usually has two components: A is the polyol blend and B is the isocyanate. This is the usage in Türkiye and Europe; in North America the letters are often reversed, so follow the drum labels. The buying options are covered in our guide Buying Polyurethane Systems from Türkiye. JiTPOL is a polyurethane system house in Bursa that develops and supplies flexible, viscoelastic and other systems.

Whichever supplier you ask, give this information:

What to tell the supplierWhy it matters
Product and use: cushion, mattress layer, car seat or packagingIt sets the foam type and the range of density and hardness
Production method and equipment: slabstock line or mouldThe system has to match the processing conditions of your line
Target density and hardness, and how they are measuredThe same density can be soft or firm, and values from different methods cannot be compared directly
Foam type: conventional, HR or memoryIt sets resilience and durability
Fire and emission requirements of your target marketFoam is combustible (EUROPUR). Fire tests apply to the finished product, for example foam with its cover, and "flame retarded" alone is not a fire class
Monthly volume, packaging and documents (technical data sheet, safety data sheet)It allows a supply plan and a safe handling check

Frequently asked questions

Sources

  1. EUROPUR: Flexible PU foam FAQ
  2. EUROPUR: Raw materials
  3. EUROPUR: What is polyurethane foam?
  4. EUROPUR: material information sheet, flexible polyurethane foam
  5. EUROPUR: Flexible polyurethane foam for mattresses
  6. PFA: What is polyurethane foam?
  7. PFA: Foam performance
  8. PFA: Furniture case study
  9. PCC: Polyols for flexible foams
  10. PFA bulletin: The importance of density
  11. PFA bulletin: Foam test methods and flammability tests
  12. Euromoulders: Moulded polyurethane
  13. ISOPA fact sheet: rebonded flexible foam
  14. Wikipedia: Polyurethane
  15. Wikipedia: Memory foam
  16. NASA Spinoff 2005: Forty-Year-Old Foam Springs Back With New Benefits
  17. ISO 2439:2008: Determination of hardness (indentation technique)
  18. Efectis: Furniture flammability test methods
  19. Commission Regulation (EU) 2020/1149 (diisocyanates, REACH Annex XVII)
Note: This article is for general information. The right density, hardness, foam type and certificates depend on the product, the production line and the target market; always check the product's technical data sheet, safety data sheet and test reports.